1. As such, these compounds do not have to be … Note that EPA will only exempt pure compounds. Complete list of VOC Exemption Rules Jump to main content An official website of the United States government. The United States Environmental Protection Agency (U.S. EPA) excludes certain organic compounds from the regulatory definition of a VOC based on the compound's negligible contribution to the formation of ground-level ozone, better known as smog. Smog is formed when VOCs photochemically react with oxides of nitrogen (NOx) in the atmosphere. An official website of the United States government. Propylene Carbonate (also specifically exempted by EPA): Propylene Carbonate is exempted as a low reactivity compound by the EPA and also qualifies for the LVP-VOC exemption. De Minimis air contaminant source exemption Ohio Administrative Code (OAC) rule 3745-15-05 The de minimis exemption excludes an air pollution source from requiring a permit if it emits less than 10 pounds per day of particulate matter, sulfur dioxide, nitrogen oxides, organic compounds, carbon monoxide, lead or any other air contaminant. Interim Guidance on Control of Volatile Organic Compounds in Ozone State Implementation Plans, SIP Training Presentations and Assistance. Contact Us to ask a question, provide feedback, or report a problem. These determinations are made by regulation and are commonly referred to as VOC Exemptions. The two rules were published in the Federal Register on September 14th and 15th , 2020. The definition for volatile organic compounds (VOC) comes from the Order adding toxic substances to Schedule 1 to the Canadian Environmental Protection Act, 1999, section 1, published in the Canada Gazette, Part II, July 2, 2003 and its amendment published June 3, 2016. Organic chemical compounds1 are everywhere in both indoor and outdoor environments because they have become essential ingredients in many products and materials. Volatile Organic Compounds (VOC's) react with nitrogen oxides on hot summer days to form ozone (smog). As you are aware, the Federal EPA has exempted these two solvents from the definition of VOC. AMP is used in a variety of applications for pigment dispersion in water-based coatings suc… Ground Level Ozone. Update: U.S. EPA Exempt Volatile Organic Compounds PAINT -The U.S. Environmental Protection Agency (EPA) has determined that certain volatile organic compounds (VOC) have been determined to have negligible photochemical reactivity (40 CFR 51.100 (s)). On August 13, 2020, EPA released its final rules rolling back standards to control methane and VOC emissions from new oil and gas facilities. The EPA lists compounds that it has determined to be negligibly reactive in its regulations as being excluded from the regulatory definition of VOCs (40 CFR 51.100 (s)), i.e., these are considered to make a negligible contribution to ground-level ozone formation. The regulatory definition of VOC, including those compounds determined to have neglible photochemical reactivity,  has been pubished in the Code of Federal Regulations Part 51.100. : Propylene Carbonate is exempted as a low reactivity compound by the EPA and also qualifies for the LVP-VOC exemption. This table shows how each list refers to the substance. The EPA has also determined that exemption of HFO-1336mzz-Z from the regulatory definition of VOC will not result in an increase of risk to human health and the environment, and, to the extent that use of this compound does United States Environmental Protection Agency. The most recent list of VOC Exemptions are available here. The U.S. EPA definition is VOCs that have a vapor pressure < 0.1 mmHg at 20 C or a melting point > 20 C and does not sublime, if the vapor pressure is not known. PC is a less aggressive solvent in certain I&I applications, but it is highly miscible and can be used in customized blends (i.e. Contact Us to ask a question, provide feedback, or report a problem. VOC exempt solvents are organic compounds that are exempt from restrictions placed on most volatile organic compounds (VOCs) in the United States. VOC Content and VOC Exemption Rules Many states defer to the South Coast Air Quality Management District of California (the air pollution regulator for the Los Angeles basin) for VOC content limits. EPA defines a VOC as “any compound of carbon, excluding carbon monoxide, carbon dioxide, carbonic acid, metallic carbides or carbonates, and ammonium carbonate, which participates in atmospheric photochemical reactions,” with the exception of chemicals that EPA has determined to have “negligible photochemical reactivity,” such as 2-amino-2-methyl-1-propanol. On October 17, 2011 and February 15, 2013, the U.S. EPA also proposed to add the following two compounds to the list of exclusions from their VOC definition:  2,3,3,3-tetrafluoropropene (HFO-1234yf)15 trans 1-chloro-3,3,3-trifluoroprop-1-ene (SolsticeTM1233zd(E))16 The U.S. EPA decision is still pending for these two compounds. Some VOCs react slowly and changes in their emissions have limited effects on local or regional ozone pollution episodes. As such, these compounds do not have to be counted toward the VOC content of coatings products. In the summer of 2014, the United States Environmental Protection Agency (EPA) revised its regulatory definition to remove AMP from being regulated as a volatile organic compound (VOC) according to the U.S. Clean Air Act on the basis that AMP makes a negligible contribution to tropospheric (ground-level) ozone formation. EPA’s Safer Choice Criteria for VOC -exempt Solvents EPA’s Safer Choice Program will allow the use of certain solvents that do not fully comply with the Safer Choice Criteria for Solvents (at http://www2.epa.gov/saferchoice/standard) in specific circumstances. Those VOCs, determined to have low photochemical reactivity by approved test methods, may be excluded as VOC for regulatory purposes. March 27, 2014 - EPA added 2-Amino-2-methyl-1-propanol (also known as AMP, CAS124-68-5) to the list of compounds excluded from the regulatory definition of VOC. It has been the EPA’s policy that organic compounds with a negligible level of reactivity should be excluded from the regulatory VOC definition so as to focus VOC control efforts on compounds that do significantly increase ozone concentrations. Car exhaust, gasoline-powered lawn and garden equipment, gasoline dispensing stations, industrial coating operations, printing shops, paints, household chemicals - are some of the sources of VOC. with DMEs). Ozone Volatile Organic Compounds (VOC) Exemptions Fact Sheets This page contains fact sheets on EPA rulings removing certain chemical compounds from being regulation as volatile organic compounds (VOC) under the Clean Air Act. On May 30, 2017, Illinois submitted, as a SIP revision, a change to the definition of VOC at 35 IAC 211.7150 in response to an EPA rulemaking in 2016 that updated an existing exemption for the compound tertiary butyl acetate Sale or distribution of a pesticide product meeting all the criteria m 40 CFR 152.25(g) without a federal registeation is not a violation of FIFRA. An official website of the United States government. Outdoors, VOCs are volatized or released into the air mostly during manufacture or use of everyday products and materials. PC is a less aggressive solvent in certain I&I applications, but it is highly miscible and can be used in customized blends (i.e. She leads the VOC exemption program and related rule making for the revision of the EPA’s regulatory definition of VOC heading a workgroup of experts on HAPs among other toxic pollutants. Federal Register references on that exemption are: 42 FR 35314 of … United States Environmental Protection Agency. However, SCAQMD Rule 102 includes VOC-exempt products which may or may not be listed as VOC-exempt by the EPA. ANGUS submitted a VOC-exemption petition to the EPA in October 2012 after tests performed at an independent lab confirmed that AMP meets or exceeds the agency’s no-VOC benchmarks. EPA does not review or issue notices of exemption for products which meet the conditions for exemption. 2. Evidence shows that AMP is negligibly reactive in forming ground-level ozone. VOC-Exempt Solvents EPA regulations include a list of compounds that are explicitly exempted from regulation as VOCs, even though they are “compounds of carbon.” These include a short list of compounds such as carbon monoxide and carbon dioxide that historically have not been regulated as VOCs, and a longer list of compounds that EPA has classified as “negligibly reactive.” Since 1977, EPA has As you are aware, the Federal EPA has exempted these two solvents from the definition of VOC. This exemption was designed to prioritize reductions in VOC compounds that most readily participate in ozone formation. The policy of excluding negligibly reactive compounds from the regulatory definition of VOC was first laid out in the “Recommended Policy on Control of Volatile Organic Compounds” (42 FR 35314, July 8, 1977) and was supplemented subsequently with the “Interim Guidance on Control of Volatile Organic Compounds in Ozone State Implementation Plans”. Volatile Organic Compounds (VOC's) react with nitrogen oxides on hot summer days to form ozone (smog). These determinations are made by regulation and are commonly referred to as VOC Exemptions. There are thousands of individual chemical species of VOCs that can react to form ozone. … Car exhaust, gasoline-powered lawn and garden equipment, gasoline dispensing stations, industrial coating operations, printing shops, paints, household chemicals - are some of the sources of VOC. To view more metadata about U.S. EPA grants AMP VOC-exempt status In 2015, the United States Environmental Protection Agency (EPA) revised its regulatory definition to remove AMP from being regulated as a VOC, allowing the product to support an environmentally conscious domestic market. Note that EPA will only exempt pure compounds. The U.S. Environmental Protection Agency (EPA) has determined that certain volatile organic compounds (VOC) have been determined to have negligible photochemical reactivity ( 40 CFR 51.100 (s) ). EPA Applications/Systems Below are the EPA applications/systems, statutes/regulations, or other sources that track or regulate this substance. This class currently includes acetone, dimethyl carbonate, methyl acetate, parachlorobenzotrifluoride (Oxsol 100), tert … https://www.govinfo.gov/content/pkg/FR-1977-07-08/pdf/FR-1977-07-08.pdf#page=148, 1,1,1 trichloroethane (methyl chloroform), Air Quality- Recommended policy on control of VOC, https://www.govinfo.gov/content/pkg/FR-1979-06-04/pdf/FR-1979-06-04.pdf#page=112, Clarification on dichloromethane (methylene chloride and/or methyl chloroform), https://www.govinfo.gov/content/pkg/FR-1980-05-16/pdf/FR-1980-05-16.pdf#page=146, https://www.govinfo.gov/content/pkg/FR-1980-07-22/pdf/FR-1980-07-22.pdf#page=103, 1,1,2-trichloro-1,2,2-trifluoroethane (CFC-113)- Trichlorotrifluoroethane, 1,2-dichloro-1,1,2,2-tetrafluoroethane (CFC-114), 1,1,1-trifluoro-2,2-dichloroethane (HCFC-123), https://www.govinfo.gov/content/pkg/FR-1989-01-18/pdf/FR-1989-01-18.pdf#page=71, 2-chloro-1,1,1,2-tetrafluoroethane (HCFC-124), https://www.govinfo.gov/content/pkg/FR-1991-03-18/pdf/FR-1991-03-18.pdf#page=80. with DMEs). CARB conducted further research to better understand impacts of LVP-VOCs emitted from the use of consumer products on ozone and secondary organic aerosol formation, and their environmental fate. VOC Exemption Story In the U.S., a compound may be excluded as a VOC as a result of public petitions and new scientific data that demonstrate its negligible effect on the formation of ground-level ozone. Indoors, VOCs are mostly released into the air from the use of products and materials containing VOCs.VOCs are of concern as both indoor air pollutants and as outdoor air pollutants. This action will allow states to remove regulatory controls on AMP that are part of State Implementation Plans designed to help meet the ground-level ozone standards. Federal Register references on that exemption are: Federal Register references on that exemption are: 42 FR 35314 of July 8, 1977 In October 2012 ANGUS submitted a petition to the EPA to exempt AMP from regulation as a VOC. Those VOCs, determined to have low photochemical reactivity by approved test methods, may be excluded as VOC for regulatory purposes. cyclic, branched, or linear, completely fluorinated alkanes; cyclic, branched, or linear, completely fluorinated ethers with no unsaturations; cyclic, branched, or linear, completely fluorinated tertiary amines with no unsaturations; and, sulfur containing perfluorocarbons with no unsaturations and with sulfur bonds only to carbon and fluorine, https://www.govinfo.gov/content/pkg/FR-1994-10-05/pdf/FR-1994-10-05.pdf#page=25, cyclic, branched, or linear completely methylated siloxanes, https://www.govinfo.gov/content/pkg/FR-1995-06-16/pdf/95-14804.pdf#page=1, https://www.govinfo.gov/content/pkg/FR-1996-02-07/pdf/96-2495.pdf#page=2, 3,3-dichloro-1,1,1,2,2-pentafluoropropane (HCFC-225ca), https://www.govinfo.gov/content/pkg/FR-1996-10-08/pdf/96-25787.pdf#page=1, 1,3-dichloro-1,1,2,2,3-pentafluoropropane (HCFC-225cb), 1,1,1,2,3,4,4,5,5,5-decafluoropentane (HFC-43-10mee), https://www.govinfo.gov/content/pkg/FR-1997-08-25/pdf/97-22510.pdf#page=1, 1,1,1,3,3,3-hexafluoropropane (HFC-236fa), 1,2-dichloro-1,1,2-trifluoroethane (HCFC-123a), 1,1,1,2,2,3,3,4,4-nonafluoro-4-methoxy-butane (C4F9OCH3), 2-(difluoromethoxymethyl)-1,1,1,2,3,3,3-heptafluoropropane ((CF3)2CFCF2OCH3), 1-ethoxy-1,1,2,2,3,3,4,4,4-nonafluorobutane (C4F9OCH2H5), 2-(ethoxydifluoromethyl)-1,1,1,2,3,3,3-heptafluoropropane ((CF3)2CFCF2OC2H5), https://www.govinfo.gov/content/pkg/FR-1998-04-09/pdf/98-9247.pdf#page=1, 1,1,1,2,2,3,3- heptafluoro-3-methoxy-propane (n-C3F7OCH3  or HFE-7000), https://www.govinfo.gov/content/pkg/FR-2004-11-29/pdf/04-26070.pdf#page=1, 3-ethoxy-1,1,1,2,3,4,4,5,5,6,6,6-dodecafluoro-2-(trifluoromethyl) hexane (HFE-7500), 1,1,1,2,3,3,3-hetafluoropropane (HFC-227ea), https://www.govinfo.gov/content/pkg/FR-2004-11-29/pdf/04-26069.pdf#page=1, 1,1,1,2,2,3,4,5,5,5-decafluoro-3-methoxy-4-trifluoromethyl-pentane (also known as HFE-7300), https://www.govinfo.gov/content/pkg/FR-2007-01-18/pdf/E7-638.pdf#page=1, https://www.govinfo.gov/content/pkg/FR-2009-01-21/pdf/E9-1150.pdf#page=1, trans-1,3,3,3-tetrafluoropropene (HFO-1234ze), https://www.govinfo.gov/content/pkg/FR-2012-06-22/pdf/2012-15347.pdf#page=1, https://www.govinfo.gov/content/pkg/FR-2013-02-12/pdf/2013-03057.pdf#page=1, HCF2OCF2OCF2CF2OCF2H (H-Galden 1040X, ZT 130, 150, or 180), trans-1-chloro-3,3,3-trifluoroprop-1-ene (SolsticeTM 1233zd(E)), https://www.govinfo.gov/content/pkg/FR-2013-08-28/pdf/2013-21014.pdf#page=1, 2,3,3,3-tetrafluoropropene   (HFO-1234yf), https://www.govinfo.gov/content/pkg/FR-2013-10-22/pdf/2013-23783.pdf#page=1, https://www.govinfo.gov/content/pkg/FR-2014-03-27/pdf/2014-06790.pdf#page=1, https://www.govinfo.gov/content/pkg/FR-2016-02-25/pdf/2016-04072.pdf#page=1, 1,1,2,2-Tetrafluoro-1-(2,2,2-trifluoroethoxy) ethane (HFE-347pcf2), https://www.govinfo.gov/content/pkg/FR-2016-08-01/pdf/2016-17790.pdf#page=1, 1,1,1,4,4,4-hexafluorobut-2-ene (HFO-1336mzz-Z), https://www.govinfo.gov/content/pkg/FR-2018-11-28/pdf/2018-25891.pdf#page=1. 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